After two years of effort, researchers are cheap and easy to obtain phenol and tetrafluoroethylene as raw material, through a series of reactions, the preparation of a variety containing perfluorinated methacrylate monomers and oligomers cyclobutyl structure material, obtained by radical polymerization polymethacrylate esters containing perfluoro cyclobutyl structure and a homopolymer of methyl methacrylate (MMA) random copolymer. High glass transition temperature of the polymer can be soluble in common organic solvents, it has good processing performance.